Here are two more villains which I think many people sympathise with:
Carver is one of the villianous Doones of R.D Blackmores Lorna Doone. The Doone's are a wild, lawless and brutal outlaws and Carver is their future leader. Carver is betrothed to the beautiful Lorna Doone and although Carver is able to have anyone he wants he truly wants Lorna because he loves her. However Lorna doesn't reciprocate these feelings, as she is in love with another man, John Ridd. Carver is extremely jealous and risks his life, that of the Doone's and jeopardises the future and the existance of the Doone hideout in order to get Lorna back from John. Carver's love for Lorna totally overtakes him and is eventually the death of him. In his last moments he is sinking in a bog and refuses to take the staff which is extended out to him by John Ridd.
Carvers life is a tragic one, he loved but never felt love, he saw everything that the generations before him work for their entire lives collapse before his eyes only after a short time in his command. However Carver's final moments show his spirit in the fact that he would never give up or give in.